Probing the correlation between phase evolution and growth kinetics in the oxide layers of tungsten using Raman spectroscopy and EBSD

التفاصيل البيبلوغرافية
العنوان: Probing the correlation between phase evolution and growth kinetics in the oxide layers of tungsten using Raman spectroscopy and EBSD
المؤلفون: Fulton, George, Lunev, Artem
سنة النشر: 2019
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Tungsten, a plasma-facing material for future fusion reactors, may be exposed to air during abnormal operation or accidents. Only limited information is available on the evolution of related oxide phases. This work addresses the effect of substrate orientation on structural variations of tungsten oxides. Annealing experiments in an argon-oxygen atmosphere have been conducted at T = 400 {\deg}C under varying oxygen partial pressure and oxidation time. A combination of EBSD, Raman spectroscopy and confocal microscopy shows preferential oxidation initially on {111} base material planes. The oxide scale changes its phase composition dynamically, influencing the kinetics of its growth.
Comment: 13 pages, 13 figures, 3 tables
نوع الوثيقة: Working Paper
DOI: 10.1016/j.corsci.2019.108221
URL الوصول: http://arxiv.org/abs/1904.04392
رقم الانضمام: edsarx.1904.04392
قاعدة البيانات: arXiv
الوصف
DOI:10.1016/j.corsci.2019.108221