Resistances for heat and mass transfer through a liquid-vapor interface in a binary mixture

التفاصيل البيبلوغرافية
العنوان: Resistances for heat and mass transfer through a liquid-vapor interface in a binary mixture
المؤلفون: Glavatskiy, Kirill, Bedeaux, Dick
سنة النشر: 2010
المجموعة: Condensed Matter
Physics (Other)
مصطلحات موضوعية: Condensed Matter - Soft Condensed Matter, Physics - Chemical Physics
الوصف: In this paper we calculate the interfacial resistances to heat and mass transfer through a liquid-vapor interface in a binary mixture. We use two methods, the direct calculation from the actual non-equilibrium solution and integral relations, derived earlier. We verify, that integral relations, being a relatively faster and cheaper method, indeed gives the same results as the direct processing of a non-equilibrium solution. Furthermore we compare the absolute values of the interfacial resistances with the ones obtained from kinetic theory. Matching the diagonal resistances for the binary mixture we find that kinetic theory underestimates the cross coefficients. The heat of transfer is as a consequence correspondingly larger.
Comment: 15 pages, 5 figures
نوع الوثيقة: Working Paper
DOI: 10.1063/1.3518368
URL الوصول: http://arxiv.org/abs/1008.3524
رقم الانضمام: edsarx.1008.3524
قاعدة البيانات: arXiv