Neonicotinoid insecticide hydrolysis and photolysis: Rates and residual toxicity

التفاصيل البيبلوغرافية
العنوان: Neonicotinoid insecticide hydrolysis and photolysis: Rates and residual toxicity
المؤلفون: Stephen A, Todey, Ann M, Fallon, William A, Arnold
المصدر: Environmental toxicology and chemistry. 37(11)
سنة النشر: 2018
مصطلحات موضوعية: Ions, Culex, Insecticides, Kinetics, Neonicotinoids, Photolysis, Metals, Hydrolysis, Larva, Toxicity Tests, Animals, Environmental Pollution, Water Pollutants, Chemical
الوصف: Neonicotinoid insecticides are the most widely used class of insecticides worldwide. Concern has grown over their widespread environmental presence and potential unintended adverse effects. The present study examined hydrolysis and photolysis reaction rates of neonicotinoids and assessed any residual toxicity of reaction products. Hydrolysis rates were tested between pH 4 and 10 and found to be base-catalyzed. Experiments revealed a nonelementary rate law for hydrolysis, with the hydroxide concentration raised to a power of 0.55 ± 0.09, which has implications for accurate prediction of environmental half-lives. Divalent metal ions (Cu
تدمد: 1552-8618
URL الوصول: https://explore.openaire.eu/search/publication?articleId=pmid________::15273039f717579aa4a3a94a537ccbf9
https://pubmed.ncbi.nlm.nih.gov/30156316
رقم الانضمام: edsair.pmid..........15273039f717579aa4a3a94a537ccbf9
قاعدة البيانات: OpenAIRE