Electrochemistry of Secondary Amine Substituted 2,5-di(2-thienyl)pyrrole Derivative and Its Copolymer
| العنوان: | Electrochemistry of Secondary Amine Substituted 2,5-di(2-thienyl)pyrrole Derivative and Its Copolymer |
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| المؤلفون: | Hakan Can Soyleyici, Ogun Gumusay, Halil Cetisli, Metin Ak, Tugba Soganci |
| المصدر: | Journal of The Electrochemical Society. 164:H421-H429 |
| بيانات النشر: | The Electrochemical Society, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Cyclic voltammetry, Materials science, Pyrrole derivatives, Conducting polymers, 02 engineering and technology, Spectroscopic analysis, 010402 general chemistry, Photochemistry, Electrochromic devices, Optical and electrical properties, 01 natural sciences, Synthesis, Electrochromic properties, chemistry.chemical_compound, 2,5-di(2-thienyl)pyrrole, PEDOT:PSS, Copolymerization, Polymer chemistry, Feed ratio, Materials Chemistry, Electrochemistry, Copolymer, Polythiophenes, Coloration efficiencies, Monomer structures, PEDOT, Pyrrole, Conductive polymer, chemistry.chemical_classification, Electrochromic materials, Electrochromism, Renewable Energy, Sustainability and the Environment, Polymer, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Copolymer compositions, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Monomer, chemistry, Hydrazine derivatives, Polymer properties, 0210 nano-technology |
| الوصف: | Since the discovery of conductive polymers, one of the most promising innovations in the field of polymer chemistry, these materials have been used in many practical applications. However, new monomers are being designed to overcome some of the disadvantages of conductive polymers, such as their inherent stability, low optical and electrical properties. It is known that minor arrangement on the monomer structure lead to very large changes in the polymer properties. In this study, a thienyl pyrrole monomer, one of the most studied monomers in the field of conductive polymers, has been produced using hydrazine derivatives instead of amines. For this purpose, the model monomer, N-phenyl-2,5-di(thiophen-2-yl)-1H-pyrrol-1-amine, was synthesized and the optical, electrochemical and electrochromic properties of its conductive polymer were investigated. Furthermore, copolymer studies with 3,4-ethylenedioxythiophene (EDOT) have been done to emphasize the importance of copolymerization on electrochromic properties of the conducting polymers. Effects of the feed ratio of the monomers and applied potential for copolymerization on optical and electrochemical properties of the electrochemically synthesized copolymers were investigated in detail. |
| وصف الملف: | application/pdf |
| تدمد: | 1945-7111 0013-4651 |
| DOI: | 10.1149/2.0291707jes |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa0129fcd962865ffff744c35182cde8 https://doi.org/10.1149/2.0291707jes |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....fa0129fcd962865ffff744c35182cde8 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 19457111 00134651 |
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| DOI: | 10.1149/2.0291707jes |