2,6-Bis(benzimidazol-2-yl)pyridines as more electron-rich and sterically accessible alternatives to 2,6-bis(imino)pyridine for group 13 coordination chemistry
| العنوان: | 2,6-Bis(benzimidazol-2-yl)pyridines as more electron-rich and sterically accessible alternatives to 2,6-bis(imino)pyridine for group 13 coordination chemistry |
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| المؤلفون: | Justin F. Binder, Riccardo Suter, Ala'aeddeen Swidan, Charles L. B. Macdonald, Blake J. St. Onge, Neil Burford |
| المصدر: | Dalton Transactions. 48:1284-1291 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Steric effects, 010405 organic chemistry, Chemistry, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, 3. Good health, 0104 chemical sciences, Coordination complex, Inorganic Chemistry, chemistry.chemical_compound, Autoionization, Group (periodic table), Pyridine |
| الوصف: | Treatment of GaCl3 with 2,6-bis(benzimidazol-2-yl)pyridine (G-BZIMPY, G = NBz, N(3,5-CF3)Bz, N-allyl and O) yielded the autoionization products [G-BZIMPYGaCl2][GaCl4] (1-4) in great yields. The Ga(iii) complex 1 was reduced to Ga(i) using K2[Fe(CO)4], resulting in the complex [(NBzBZIMPY)(Cl)Ga-Fe(CO)4] (7). GaCl3 and AlCl3 were complexed by the structurally similar bis(imino)pyridine (DIMPY) and the resulting complexes are compared to those of G-BZIMPY. |
| تدمد: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c8dt04276d |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f4596eefe3ce263b498b40cda348bee6 https://doi.org/10.1039/c8dt04276d |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....f4596eefe3ce263b498b40cda348bee6 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14779234 14779226 |
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| DOI: | 10.1039/c8dt04276d |