Poly(vinylidene chloride)-Based Amphiphilic Block Copolymers
| العنوان: | Poly(vinylidene chloride)-Based Amphiphilic Block Copolymers |
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| المؤلفون: | Pierre-Emmanuel Dufils, Muriel Lansalot, Bernadette Charleux, François Stoffelbach, Gaëlle Pembouong, Jérôme Vinas, Franck D'Agosto, Jutta Rieger, Emilie Velasquez, Olivier Boyron |
| المساهمون: | Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265 (C2P2), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École Supérieure de Chimie Physique Électronique de Lyon (CPE)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Chimie des polymères (LCP), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut Parisien de Chimie Moléculaire (IPCM), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Solvay, Centre National de la Recherche Scientifique (CNRS)-École supérieure de Chimie Physique Electronique de Lyon (CPE)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC) |
| المصدر: | Macromolecules Macromolecules, 2013, 46 (3), pp.664-673. ⟨10.1021/ma302339x⟩ Macromolecules, American Chemical Society, 2013, 46 (3), pp.664-673. ⟨10.1021/ma302339x⟩ BASE-Bielefeld Academic Search Engine |
| بيانات النشر: | HAL CCSD, 2013. |
| سنة النشر: | 2013 |
| مصطلحات موضوعية: | Polymers and Plastics, Comonomer, Organic Chemistry, Chain transfer, 02 engineering and technology, Raft, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Chloride, 0104 chemical sciences, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Amphiphile, Polymer chemistry, Materials Chemistry, medicine, Copolymer, [CHIM]Chemical Sciences, 0210 nano-technology, Methyl acrylate, ComputingMilieux_MISCELLANEOUS, medicine.drug, Acrylic acid |
| الوصف: | The controlled/living free-radical copolymerization of vinylidene chloride (VDC) with methyl acrylate (MeA) or acrylic acid (AA) was studied by the reversible addition–fragmentation chain transfer (RAFT) technique using a trithiocarbonate RAFT agent. The reactions were performed in 1,4-dioxane solution at 30 °C and led to good control and high chain-end functionality. P(VDC-co-MeA)-b-PAA, PAA-b-P(VDC-co-MeA), and PAA-b-P(VDC-co-AA) amphiphilic block copolymers were then prepared in the same conditions, starting either from a hydrophobic P(VDC-co-MeA) macromolecular RAFT (macro-RAFT) agent or from a hydrophilic PAA one. The advantage of the first synthesis pathway relies on the very good transfer efficiency to trithiocarbonate-ended P(VDC-co-MeA) and on the rapid consumption of the latter even when low percentages (10 mol %) of MeA comonomer are incorporated in the macro-RAFT agent. In contrast, for the second approach a rapid consumption of the macro-RAFT agent is only reached with 30 mol % of MeA in the ... |
| اللغة: | English |
| تدمد: | 0024-9297 1520-5835 |
| DOI: | 10.1021/ma302339x⟩ |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e8ac2e9c41744b4ee757d9c5e0073102 https://hal.science/hal-01877406 |
| رقم الانضمام: | edsair.doi.dedup.....e8ac2e9c41744b4ee757d9c5e0073102 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 00249297 15205835 |
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| DOI: | 10.1021/ma302339x⟩ |