Functionalizing aromatic compounds with optical cycling centres
| العنوان: | Functionalizing aromatic compounds with optical cycling centres |
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| المؤلفون: | Guo-Zhu Zhu, Debayan Mitra, Benjamin L. Augenbraun, Claire E. Dickerson, Michael J. Frim, Guanming Lao, Zack D. Lasner, Anastassia N. Alexandrova, Wesley C. Campbell, Justin R. Caram, John M. Doyle, Eric R. Hudson |
| المصدر: | Nature chemistry, vol 14, iss 9 |
| بيانات النشر: | Springer Science and Business Media LLC, 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Chemical Physics (physics.chem-ph), Photons, Molecular Structure, Light, Atomic Physics (physics.atom-ph), Lasers, General Chemical Engineering, physics.chem-ph, Organic Chemistry, FOS: Physical sciences, General Chemistry, physics.atom-ph, Physics - Atomic Physics, 1.3 Chemical and physical sciences, Quantum Gases (cond-mat.quant-gas), Underpinning research, Physics - Chemical Physics, Chemical Sciences, Organic Chemicals, Condensed Matter - Quantum Gases, cond-mat.quant-gas |
| الوصف: | Molecular design principles provide guidelines for augmenting a molecule with a smaller group of atoms to realize a desired property or function. We demonstrate that these concepts can be used to create an optical cycling center that can be attached to a number of aromatic ligands, allowing the scattering of many photons from the resulting molecules without changing the molecular vibrational states. We provide further design principles that indicate the ability to expand this work. This represents a significant step towards a quantum functional group, which may serve as a generic qubit moiety that can be attached to a wide range of molecular structures and surfaces. 6 pages, 3 figures |
| وصف الملف: | application/pdf |
| تدمد: | 1755-4349 1755-4330 |
| DOI: | 10.1038/s41557-022-00998-x |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de0104cf4e39beca834efbd77e4a4a20 https://doi.org/10.1038/s41557-022-00998-x |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....de0104cf4e39beca834efbd77e4a4a20 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 17554349 17554330 |
|---|---|
| DOI: | 10.1038/s41557-022-00998-x |