tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide
| العنوان: | tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide |
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| المؤلفون: | Marcella Bosco, Paolo Melchiorre, Giuseppe Bartoli, Enrico Marcantoni, Letizia Sambri, Manuela Locatelli, Armando Carlone |
| المساهمون: | G. Bartoli, M. Bosco, A. Carlone, M. Locatelli, E. Marcantoni, P. Melchiorre, L. Sambri |
| المصدر: | Advanced Synthesis & Catalysis. 348:905-910 |
| بيانات النشر: | Wiley, 2006. |
| سنة النشر: | 2006 |
| مصطلحات موضوعية: | tert-butyl ethers, CERIUM(III), Cerium(III) chloride/sodium iodide system, Organic Chemistry, Alcohol, General Medicine, General Chemistry, Cleavage (embryo), Catalysis, chemistry.chemical_compound, Deprotection, chemistry, Chemistry (miscellaneous), Alcohols, Sodium iodide, Protecting groups, Anhydrous, Organic chemistry, Molecule, Cerium(III) chloride, Protecting group, Derivative (chemistry) |
| الوصف: | The tert-butoxy derivative is one of the most underused alcohol protectingg roups. After havingdeveloped an easy and useful protocol for its introduction, we offer here a simple procedure for its removal by treatment with anhydrous CeCl3 and NaI in CH3CN. The procedure led to the successful cleavage of aliphatic and aromatic tert-butyl ethers and was compatible with various other functionalities and protecting groups present in the molecule. |
| وصف الملف: | STAMPA |
| تدمد: | 1615-4169 1615-4150 |
| DOI: | 10.1002/adsc.200505469 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d15645479fddd16f416c385fc5995747 https://doi.org/10.1002/adsc.200505469 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....d15645479fddd16f416c385fc5995747 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16154169 16154150 |
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| DOI: | 10.1002/adsc.200505469 |