Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand
| العنوان: | Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand |
|---|---|
| المؤلفون: | Jeffrey M. Barlow, William J. Evans, Daniel N. Huh, Joseph W. Ziller, Jenny Y. Yang, Sierra R. Ciccone |
| المصدر: | Inorganic Chemistry. 59:17077-17083 |
| بيانات النشر: | American Chemical Society (ACS), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | Inorganic Chemistry, chemistry.chemical_compound, Hydrolysis, chemistry, Crypt, Dimethylformamide, Physical and Theoretical Chemistry, Acetonitrile, Electrochemistry, 2.2.2-Cryptand, Nuclear chemistry |
| الوصف: | The electrochemical properties of U(III)-in-crypt (crypt = 2.2.2-cryptand) were examined in dimethylformamide (DMF) and acetonitrile (MeCN) to determine the oxidative stability offered by crypt as a ligand. Cyclic voltammetry revealed a U(III)/U(IV) irreversible oxidation at |
| تدمد: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.0c02286 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd6de8a45161d4fc3563a650eae02ca1 https://doi.org/10.1021/acs.inorgchem.0c02286 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....cd6de8a45161d4fc3563a650eae02ca1 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1520510X 00201669 |
|---|---|
| DOI: | 10.1021/acs.inorgchem.0c02286 |