التفاصيل البيبلوغرافية
| العنوان: |
Mechanochemical synthesis of hyper-crosslinked polymers: influences on their pore structure and adsorption behaviour for organic vapors |
| المؤلفون: |
Marcus Rose, Sebastian Zink, Lars Borchardt, Hanna Kraffczyk, Sven Grätz |
| المصدر: |
Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 1154-1161 (2019)
Beilstein Journal of Organic Chemistry |
| بيانات النشر: |
Beilstein-Institut zur F��rderung der Chemischen Wissenschaften, 2021. |
| سنة النشر: |
2021 |
| مصطلحات موضوعية: |
chemistry.chemical_classification, Cyclohexane, microporous, Organic Chemistry, Sorption, Polymer, Microporous material, solvent-free, Full Research Paper, Solvent, lcsh:QD241-441, chemistry.chemical_compound, Chemistry, Adsorption, chemistry, Chemical engineering, Polymerization, lcsh:Organic chemistry, Mechanochemistry, vapor sorption, lcsh:Q, mechanochemistry, hyper-crosslinked polymers, lcsh:Science |
| الوصف: |
This study elucidates a mechanochemical polymerization reaction towards a hyper-crosslinked polymer as an alternative to conventional solvent-based procedures. The swift and solvent-free Friedel–Crafts alkylation reaction yields a porous polymer with surface areas of up to 1720 m2g−1 and pore volumes of up to 1.55 cm3g−1. The application of LAG (liquid-assisted grinding) revealed a profound impact of the liquid´s boiling point on the textural properties of the obtained polymer materials. Finally, the materials are characterized by vapour sorption experiments with benzene and cyclohexane. |
| وصف الملف: |
text |
| DOI: |
10.26083/tuprints-00019905 |
| URL الوصول: |
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aef49e95a88eeccacb7e668eed81af99 |
| Rights: |
OPEN |
| رقم الانضمام: |
edsair.doi.dedup.....aef49e95a88eeccacb7e668eed81af99 |
| قاعدة البيانات: |
OpenAIRE |