High Tolerance to Iron Contamination in Lead Halide Perovskite Solar Cells

التفاصيل البيبلوغرافية
العنوان: High Tolerance to Iron Contamination in Lead Halide Perovskite Solar Cells
المؤلفون: Vladimir Bulovic, Moungi G. Bawendi, Vladan Stevanović, Juan-Pablo Correa-Baena, Robert L. Z. Hoye, Tonio Buonassisi, Jeremy R. Poindexter, Anna Osherov, Ashley E. Morishige, Lea Nienhaus, Rachel C. Kurchin, Erin E. Looney, Barry Lai
المصدر: ACS nano. 11(7)
سنة النشر: 2017
مصطلحات موضوعية: Materials science, Photoluminescence, Silicon, Inorganic chemistry, General Physics and Astronomy, Halide, chemistry.chemical_element, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, law.invention, Impurity, law, Photovoltaics, Solar cell, General Materials Science, Perovskite (structure), business.industry, General Engineering, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Semiconductor, chemistry, Optoelectronics, 0210 nano-technology, business
الوصف: The relationship between charge-carrier lifetime and the tolerance of lead halide perovskite (LHP) solar cells to intrinsic point defects has drawn much attention by helping to explain rapid improvements in device efficiencies. However, little is known about how charge-carrier lifetime and solar cell performance in LHPs are affected by extrinsic defects (i.e., impurities), including those that are common in manufacturing environments and known to introduce deep levels in other semiconductors. Here, we evaluate the tolerance of LHP solar cells to iron introduced via intentional contamination of the feedstock and examine the root causes of the resulting efficiency losses. We find that comparable efficiency losses occur in LHPs at feedstock iron concentrations approximately 100 times higher than those in p-type silicon devices. Photoluminescence measurements correlate iron concentration with nonradiative recombination, which we attribute to the presence of deep-level iron interstitials, as calculated from first-principles, as well as iron-rich particles detected by synchrotron-based X-ray fluorescence microscopy. At moderate contamination levels, we witness prominent recovery of device efficiencies to near-baseline values after biasing at 1.4 V for 60 s in the dark. We theorize that this temporary effect arises from improved charge-carrier collection enhanced by electric fields strengthened from ion migration toward interfaces. Our results demonstrate that extrinsic defect tolerance contributes to high efficiencies in LHP solar cells, which inspires further investigation into potential large-scale manufacturing cost savings as well as the degree of overlap between intrinsic and extrinsic defect tolerance in LHPs and "perovskite-inspired" lead-free stable alternatives.
تدمد: 1936-086X
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8b06b79b0d1e6ba96533ab1421498b30
https://pubmed.ncbi.nlm.nih.gov/28657723
Rights: OPEN
رقم الانضمام: edsair.doi.dedup.....8b06b79b0d1e6ba96533ab1421498b30
قاعدة البيانات: OpenAIRE