A total synthesis of galbonolide B

التفاصيل البيبلوغرافية
العنوان: A total synthesis of galbonolide B
المؤلفون: James John Eshelby, and Adrian Highton, Peter B. Hitchcock, Matthias Goessman, Philip J. Parsons, Lewis E. Pennicott
المصدر: The Journal of organic chemistry. 72(24)
سنة النشر: 2007
مصطلحات موضوعية: Antifungal Agents, Alkylation, Stereochemistry, Propanols, Organic Chemistry, Acetal, Acetoacetic ester synthesis, Total synthesis, Alcohol, Allylic alcohol, Acetates, chemistry.chemical_compound, Lactones, Acetals, chemistry, Fragmentation (mass spectrometry), Models, Chemical, Cyclization, Galbonolide B
الوصف: An ester enolate rearrangement/silicon mediated fragmentation cascade was used to convert 7 and 8 into the alcohol 9. The alcohol 9 was converted into the allylic alcohol 12 and then to the ester 14. A further ester enolate rearrangement furnished the stereochemical identity of galbonolide B 1. Base mediated macrocyclization of the acetate ester 16 followed by base mediated alkylation and acetal deprotection gave galbonolide B 1.
تدمد: 0022-3263
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::85afc8d64bbc4401ceb68981761a66f3
https://pubmed.ncbi.nlm.nih.gov/17958371
رقم الانضمام: edsair.doi.dedup.....85afc8d64bbc4401ceb68981761a66f3
قاعدة البيانات: OpenAIRE