MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
| العنوان: | MOF-enabled confinement and related effects for chemical catalyst presentation and utilization |
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| المؤلفون: | Jian Liu, Timothy A. Goetjen, Qining Wang, Julia G. Knapp, Megan C. Wasson, Ying Yang, Zoha H. Syed, Massimiliano Delferro, Justin M. Notestein, Omar K. Farha, Joseph T. Hupp |
| المصدر: | Chemical Society Reviews. 51:1045-1097 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Ions, Molecular Conformation, General Chemistry, Catalysis |
| الوصف: | A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and product transport, catalyst siting, catalyst accessibility, catalyst stability, catalyst activity, co-catalyst proximity, composition of the chemical environment at and beyond the catalytic active site, chemical intermediate and transition-state conformations, thermodynamic affinity of molecular guests for MOF interior sites, framework charge and density of charge-compensating ions, pore hydrophobicity/hydrophilicity, pore and channel rigidity |
| تدمد: | 1460-4744 0306-0012 |
| DOI: | 10.1039/d1cs00968k |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7e1a640b29c91f2df376bb5215460879 https://doi.org/10.1039/d1cs00968k |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....7e1a640b29c91f2df376bb5215460879 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14604744 03060012 |
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| DOI: | 10.1039/d1cs00968k |