Crystal structure of fac-tricarbonyl(cyclohexyl isocyanide-κC)(quinoline-2-carboxylato-κ2N,O)rhenium(I)
| العنوان: | Crystal structure of fac-tricarbonyl(cyclohexyl isocyanide-κC)(quinoline-2-carboxylato-κ2N,O)rhenium(I) |
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| المؤلفون: | Minas Papadopoulos, Vassilis Psycharis, Antonio Shegani, Catherine P. Raptopoulou, Maria Pelecanou, Christos Kiritsis, Charalampos Triantis, Ioannis Pirmettis |
| المصدر: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 3, Pp 358-362 (2016) Acta Crystallographica Section E: Crystallographic Communications |
| بيانات النشر: | International Union of Crystallography, 2016. |
| سنة النشر: | 2016 |
| مصطلحات موضوعية: | crystal structure, Denticity, Coordination sphere, Stereochemistry, Trans effect, Isocyanide, rhenium(I) cyclohexyl isocyanide and quinaldic acid complex, rhenium(I) tricarbonyl complex, Crystal structure, 010402 general chemistry, 01 natural sciences, Research Communications, chemistry.chemical_compound, Hirshfeld surface analysis, General Materials Science, rhenium(I) cyclohexyl isocyanide and quinaldic acid complex, Crystallography, 010405 organic chemistry, Ligand, Tricarbon, Quinoline, General Chemistry, Condensed Matter Physics, 0104 chemical sciences, structural trans effect, chemistry, QD901-999 |
| الوصف: | The ReI atom in the molecule of the title compound has a distorted C4NO coordination sphere defined by three carbonyl ligands, one chelating quinaldate anion and one isocyanide ligand. As a result of the trans effect of the isocyanide derivative, one Re—CO bond is elongated. In the title compound, [Re(C10H6NO2)(C7H11N)(CO)3], the ReI atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octahedral. A lengthening of the axial Re—CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π–π interactions. Weak C—H⋯O hydrogen-bonding interactions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [010] by C—H⋯H—C van der Waals contacts. |
| اللغة: | English |
| تدمد: | 2056-9890 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c7e7d171ce27c2a9eee82e2c4e9ff24 http://scripts.iucr.org/cgi-bin/paper?S2056989016002206 |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....7c7e7d171ce27c2a9eee82e2c4e9ff24 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 20569890 |
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