Pd/TiO2 doped faujasite photocatalysts for acetophenone transfer hydrogenation in a photocatalytic membrane reactor
| العنوان: | Pd/TiO2 doped faujasite photocatalysts for acetophenone transfer hydrogenation in a photocatalytic membrane reactor |
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| المؤلفون: | Teresa F. Mastropietro, Raffaele Molinari, Teresa Poerio, Giuseppe Pirri, Cristina Lavorato, Pietro Argurio |
| المصدر: | Journal of catalysis 353 (2017): 152–161. doi:10.1016/j.jcat.2017.07.015 info:cnr-pdr/source/autori:Lavorato, Cristina; Argurio, Pietro; Mastropietro, Teresa F.; Pirri, Giuseppe; Poerio, Teresa; Molinari, Raffaele/titolo:Pd%2FTiO2 doped faujasite photocatalysts for acetophenone transfer hydrogenation in a photocatalytic membrane reactor/doi:10.1016%2Fj.jcat.2017.07.015/rivista:Journal of catalysis (Print)/anno:2017/pagina_da:152/pagina_a:161/intervallo_pagine:152–161/volume:353 |
| بيانات النشر: | Academic Press., San Diego [etc.], Stati Uniti d'America, 2017. |
| سنة النشر: | 2017 |
| مصطلحات موضوعية: | Inorganic chemistry, 02 engineering and technology, engineering.material, 010402 general chemistry, Transfer hydrogenation, Photochemistry, 01 natural sciences, Catalysis, chemistry.chemical_compound, Sustainable chemistry, Physical and Theoretical Chemistry, Photocatalysis, Doped titanium dioxide, Zeolite, Chemistry, Faujasite, 021001 nanoscience & nanotechnology, Photocatalytic membrane reactors, 0104 chemical sciences, Light intensity, engineering, Ketone hydrogenation, 0210 nano-technology, Energy source, Visible spectrum, Acetophenone |
| الوصف: | Different titanium faujasite photocatalysts have been prepared and tested in the transfer hydrogenation of acetophenone to phenyl ethanol, an industrially relevant product. Water as solvent, formic acid as hydrogen and electron donor and UV and visible light irradiation, have been employed. The 10% loaded titanium faujasite prepared using propanol as solvent (TF10P) showed the best homogeneous dispersion of TiO2 particles on the zeolite surface, BET and pore volume values and photocatalytic performance. A further functionalization of the TF10P photocatalyst with Pd particles (Pd_TF10P), shifted the catalytic response in the visible range. The productivity, normalized by the light intensity, obtained by using the Pd_TF10P photocatalyst under visible light was a little lower than that obtained by using the TF10P under UV light (12.56 mg g(TiO2)(-1) h(-1) cm(2) W-1 vs 19.11 mg g(TiO2)(-1) h(-1) cm(2) W-1) but the advantage could be the use of direct solar ligth as energy source. The photocatalytic membrane reactor had an extraction percentage of phenylethanol from the reactive phase to the organic phase of ca. 25%. The results also evidenced the possibility to use the visible light in this photocatalytic system in the photo-catalytic reduction of acetophenone. (C) 2017 Elsevier Inc. All rights reserved. |
| اللغة: | English |
| DOI: | 10.1016/j.jcat.2017.07.015 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7bb8cc011d079ea69457b068c7dd7fd8 http://www.cnr.it/prodotto/i/382203 |
| Rights: | RESTRICTED |
| رقم الانضمام: | edsair.doi.dedup.....7bb8cc011d079ea69457b068c7dd7fd8 |
| قاعدة البيانات: | OpenAIRE |
| DOI: | 10.1016/j.jcat.2017.07.015 |
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