Programmed folding into spiro-multicyclic polymer topologies from linear and star-shaped chains

التفاصيل البيبلوغرافية
العنوان: Programmed folding into spiro-multicyclic polymer topologies from linear and star-shaped chains
المؤلفون: Kohei Honda, Brian J. Ree, Takuya Yamamoto, Yoshinobu Mato, Kenji Tajima, Takuya Isono, Toshifumi Satoh, Tetsuo Deguchi
المصدر: Communications Chemistry, Vol 3, Iss 1, Pp 1-7 (2020)
بيانات النشر: Nature Publishing Group, 2020.
سنة النشر: 2020
مصطلحات موضوعية: chemistry.chemical_classification, Materials science, Nanostructure, 010405 organic chemistry, Dispersity, General Chemistry, Polymer, 010402 general chemistry, Metathesis, Ring (chemistry), 01 natural sciences, Biochemistry, Combinatorial chemistry, 0104 chemical sciences, Folding (chemistry), lcsh:Chemistry, chemistry, lcsh:QD1-999, Intramolecular force, Materials Chemistry, Environmental Chemistry, Trefoil
الوصف: The development of precise folding techniques for synthetic polymer chains that replicate the unique structures and functions of biopolymers has long been a key challenge. In particular,spiro-type (i.e., 8-, trefoil-, and quatrefoil-shaped) polymer topologies remain challenging due to their inherent structural complexity. Herein, we establish a folding strategy to producespiro-type multicyclic polymers via intramolecular ring-opening metathesis oligomerization of the norbornenyl groups attached at predetermined positions along a synthetic polymer precursor. This strategy provides easy access to the desiredspiro-type topological polymers with a controllable number of ring units and molecular weight while retaining narrow dispersity (& x189; < 1.1). This effective strategy marks an advancement in the development of functionalized materials composed of specific three-dimensional nanostructures. Intramolecular ring-opening metathesis oligomerisation is a useful method for constructing multicyclic polymer cages. Here, it is applied to the synthesis of spirocyclic polymers with figure-8, trefoil, and quatrefoil structures with low polydispersity.
اللغة: English
تدمد: 2399-3669
DOI: 10.1038/s42004-020-00355-4
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::76d2f392778d529ca217680d1250944f
http://link.springer.com/article/10.1038/s42004-020-00355-4
Rights: OPEN
رقم الانضمام: edsair.doi.dedup.....76d2f392778d529ca217680d1250944f
قاعدة البيانات: OpenAIRE
الوصف
تدمد:23993669
DOI:10.1038/s42004-020-00355-4