Slight pressure imbalances can affect accuracy and precision of dual inlet-based clumped isotope analysis

التفاصيل البيبلوغرافية
العنوان: Slight pressure imbalances can affect accuracy and precision of dual inlet-based clumped isotope analysis
المؤلفون: Sven Hofmann, Niklas Löffler, Tina Lüdecke, Katharina Methner, Jens Fiebig, Ulrike Wacker
المصدر: Isotopes in environmental and health studies. 52(1-2)
سنة النشر: 2015
مصطلحات موضوعية: Ion beam, Analytical chemistry, Carbonates, Faraday cup, Oxygen Isotopes, 010502 geochemistry & geophysics, 01 natural sciences, Secondary electrons, Mass Spectrometry, Ion, Inorganic Chemistry, symbols.namesake, Pressure, Environmental Chemistry, 0105 earth and related environmental sciences, General Environmental Science, Oxygen-18, Carbon Isotopes, Isotope, Chemistry, 010401 analytical chemistry, Carbon-13, Carbon Dioxide, Carbon, 0104 chemical sciences, Oxygen, symbols, Atomic physics, Beam (structure)
الوصف: It is well known that a subtle nonlinearity can occur during clumped isotope analysis of CO2 that - if remaining unaddressed - limits accuracy. The nonlinearity is induced by a negative background on the m/z 47 ion Faraday cup, whose magnitude is correlated with the intensity of the m/z 44 ion beam. The origin of the negative background remains unclear, but is possibly due to secondary electrons. Usually, CO2 gases of distinct bulk isotopic compositions are equilibrated at 1000 °C and measured along with the samples in order to be able to correct for this effect. Alternatively, measured m/z 47 beam intensities can be corrected for the contribution of secondary electrons after monitoring how the negative background on m/z 47 evolves with the intensity of the m/z 44 ion beam. The latter correction procedure seems to work well if the m/z 44 cup exhibits a wider slit width than the m/z 47 cup. Here we show that the negative m/z 47 background affects precision of dual inlet-based clumped isotope measurements of CO2 unless raw m/z 47 intensities are directly corrected for the contribution of secondary electrons. Moreover, inaccurate results can be obtained even if the heated gas approach is used to correct for the observed nonlinearity. The impact of the negative background on accuracy and precision arises from small imbalances in m/z 44 ion beam intensities between reference and sample CO2 measurements. It becomes the more significant the larger the relative contribution of secondary electrons to the m/z 47 signal is and the higher the flux rate of CO2 into the ion source is set. These problems can be overcome by correcting the measured m/z 47 ion beam intensities of sample and reference gas for the contributions deriving from secondary electrons after scaling these contributions to the intensities of the corresponding m/z 49 ion beams. Accuracy and precision of this correction are demonstrated by clumped isotope analysis of three internal carbonate standards. The proposed correction scheme can be easily applied if the slit width of the m/z 49 Faraday cup is bigger than that of the m/z 47 cup.
تدمد: 1477-2639
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b7729cc6fcc80116daae0ef172c602f
https://pubmed.ncbi.nlm.nih.gov/25685933
رقم الانضمام: edsair.doi.dedup.....6b7729cc6fcc80116daae0ef172c602f
قاعدة البيانات: OpenAIRE