Synthetic Approaches to Anti-Inflammatory Macrolactones of the Oxacyclododecindione Type

التفاصيل البيبلوغرافية
العنوان: Synthetic Approaches to Anti-Inflammatory Macrolactones of the Oxacyclododecindione Type
المؤلفون: Markus Rohr, Kristina Rudolph, Johannes Tauber, Till Opatz, Gerhard Erkel
المصدر: European Journal of Organic Chemistry. 2015:3587-3608
بيانات النشر: Wiley, 2015.
سنة النشر: 2015
مصطلحات موضوعية: chemistry.chemical_classification, Double bond, Stereochemistry, medicine.drug_class, Organic Chemistry, Hydroacylation, Total synthesis, Metathesis, Ring (chemistry), Anti-inflammatory, Ring-closing metathesis, chemistry, medicine, Physical and Theoretical Chemistry, Isomerization
الوصف: Various synthetic approaches to the oxacyclododecindione-type macrolactones, known for their potent anti-inflammatory activity, are presented. These include an attempted carbonylative ring closure, a hydroacylation route, and an approach by ring-closing metathesis and double bond isomerization, as well as a strategy including ring-closing metathesis/unsaturation. The last route allowed the preparation of a bioactive analogue of the recently described 14-deoxyoxacyclododecindione.
تدمد: 1434-193X
DOI: 10.1002/ejoc.201500275
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::58df475e227ab2892d0ca89ac9dc8512
https://doi.org/10.1002/ejoc.201500275
Rights: OPEN
رقم الانضمام: edsair.doi.dedup.....58df475e227ab2892d0ca89ac9dc8512
قاعدة البيانات: OpenAIRE
الوصف
تدمد:1434193X
DOI:10.1002/ejoc.201500275