Electrocaloric Performance of Multilayer Ceramic Chips: Effect of Geometric Structure Induced Internal Stress
| العنوان: | Electrocaloric Performance of Multilayer Ceramic Chips: Effect of Geometric Structure Induced Internal Stress |
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| المؤلفون: | Xiangming Xiong, Xin Chen, Li Qian Cheng, Mohan Sanghadasa, Xiaotian Li, Wenjie Li, Shashank Priya, Li Feng Zhu, Yongke Yan, Kai Chen |
| المصدر: | ACS Applied Materials & Interfaces. 13:38508-38516 |
| بيانات النشر: | American Chemical Society (ACS), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Materials science, Clamping, Thermal expansion, law.invention, Stress (mechanics), Capacitor, law, Electric field, visual_art, visual_art.visual_art_medium, General Materials Science, Ceramic, Composite material, Shrinkage, Voltage |
| الوصف: | Driven by an ever-growing demand for environmentally benign cooling systems, the past decade has witnessed the booming development in the field of electrocaloric (EC) cooling technology, which is considered as a promising solid-state cooling approach. Multilayer ceramic chip capacitors (MLCCs) represent the optimum structure for EC cooling elements because of large breakdown strengths, low driving voltages, and high macroscopic volumes of active EC materials. However, fundamental relationships between the geometric parameters of MLCCs and the EC coefficient are less understood. In this study, 0.92Pb(Mg1/3Nb2/3)O3-0.08PbTiO3 (PMN-PT) MLCCs with controlled configurations, such as active/inactive layer thickness, number of layers, and active volume ratio, were fabricated, and their EC performance was evaluated. The electric properties of the MLCCs are confirmed to be closely related to the geometric structure, which influences not only the heat flow but also the internal stress, resulting in the variability of EC performance and reliability/breakdown strength. The internal stress arises due to the residual thermal stress originating from the densification-related shrinkage, thermal expansion mismatch during the sintering, and clamping stress arising from the inactive area due to the large strain from the active area under a high electric field. The geometric structure-based stress distribution and the magnitude of stress on the active layers in MLCCs were determined by finite element modeling (FEM) and correlated with the experimental EC coefficients. The results reveal that a low inactive volume percentage is beneficial toward increasing the breakdown field and enhancement of EC performance because of reduced clamping stress on active EC material. |
| تدمد: | 1944-8252 1944-8244 |
| DOI: | 10.1021/acsami.1c09911 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::55210294b122d08cc17cb1986220b7ec https://doi.org/10.1021/acsami.1c09911 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....55210294b122d08cc17cb1986220b7ec |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 19448252 19448244 |
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| DOI: | 10.1021/acsami.1c09911 |