Strongly Coupled Quantum Heat Machines

التفاصيل البيبلوغرافية
العنوان: Strongly Coupled Quantum Heat Machines
المؤلفون: Alán Aspuru-Guzik, David Gelbwaser-Klimovsky
المصدر: The Journal of Physical Chemistry Letters. 6:3477-3482
بيانات النشر: American Chemical Society (ACS), 2015.
سنة النشر: 2015
مصطلحات موضوعية: Physics, Strongly coupled, Quantum Physics, Work (thermodynamics), Coupling (physics), Quantum mechanics, Evolution equation, Strong coupling, Energy transformation, General Materials Science, Limit (mathematics), Physical and Theoretical Chemistry, Quantum
الوصف: Energy conversion of heat into work at the quantum level is modeled by quantum heat machines (QHMs) generally assumed to operate at weak coupling to the baths. This supposition is grounded in the separability principle between systems and allows the derivation of the evolution equation. In the weak coupling regime, the machine's output is limited by the coupling strength, restricting their application. Seeking to overcome this limitation, we analyze QHMs in the virtually unexplored strong coupling regime here, where separability, as well as other standard thermodynamic assumptions, may no longer hold. We show that strongly coupled QHMs may be as efficient as their weakly coupled counterparts. In addition, we find a novel turnover behavior where their output saturates and disappears in the limit of ultrastrong coupling.
تدمد: 1948-7185
DOI: 10.1021/acs.jpclett.5b01404
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::52efb8cfb1dc631336ebc14e987aed2c
https://doi.org/10.1021/acs.jpclett.5b01404
Rights: OPEN
رقم الانضمام: edsair.doi.dedup.....52efb8cfb1dc631336ebc14e987aed2c
قاعدة البيانات: OpenAIRE
الوصف
تدمد:19487185
DOI:10.1021/acs.jpclett.5b01404