Whereas classical physics generally predicts an exponential trend for the temporal decay of an unstable state, quantum mechanics provides a rather different description. The decay is initially quadratic, while at very large times it follows a power-law. Actually, the latter regime has never been observed experimentally. Here we employ arrays of femtosecond-laser-written optical waveguides to optically realize quantum systems where a discrete state is coupled to and can decay into a continuum. The transverse optical modes represent distinct quantum states of the photon and the temporal evolution of the system is mapped into the longitudinal propagation coordinate. By injecting laser light in the fabricated structures, and by imaging with high dynamic range the scattered light from above, we are able to observe experimentally different decay regimes, including the power-law tail. This process can be viewed as the quantum simulation of a quantum decay phenomenon.