Hybrid 2D nanofibers based on poly(ethylene oxide)/ polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents
| العنوان: | Hybrid 2D nanofibers based on poly(ethylene oxide)/ polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents |
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| المؤلفون: | Viraj P. Nirwan, Amir Fahmi, Souvik Pandey, Evamarie Hey-Hawkins |
| المساهمون: | Laboratoire Lasers, Plasmas et Procédés photoniques (LP3), Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU) |
| المصدر: | Journal of Applied Polymer Science Journal of Applied Polymer Science, 2019, 137 (37), pp.49091. ⟨10.1002/app.49091⟩ Journal of Applied Polymer Science, Wiley, 2019, 137 (37), pp.49091. ⟨10.1002/app.49091⟩ |
| بيانات النشر: | HAL CCSD, 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Thermogravimetric analysis, Materials science, Polymers and Plastics, Infrared spectroscopy, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, chemistry.chemical_compound, Differential scanning calorimetry, [PHYS.PHYS.PHYS-PLASM-PH]Physics [physics]/Physics [physics]/Plasma Physics [physics.plasm-ph], Materials Chemistry, Thermal stability, chemistry.chemical_classification, [PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics], General Chemistry, Polymer, 021001 nanoscience & nanotechnology, Electrospinning, 0104 chemical sciences, Surfaces, Coatings and Films, chemistry, Chemical engineering, Nanofiber, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Polystyrene, 0210 nano-technology |
| الوصف: | International audience; emplate smart inorganic polymers within an organic polymeric matrix to form hybrid nanostructured materials are a unique approach to induce novel multifunctionality. In particular, the fabrication of one‐dimensional materials via electrospinning is an advanced tool, which has gained success in fulfilling the purpose to fabricate two‐dimensional nanostructured materials. We have explored the formation of novel hybrid nanofibers by co‐spinning of poly(ferrocenylphosphinoboranes) Fe A [{Fe(C5H5)(C5H4CH2PHBH2)} n] and Fe B [{Fe(C5H5)(C5H4PHBH2)} n] with poly(ethylene oxide) (PEO) and polystyrene (PS). Fe A and Fe B contain main‐group elements and a ferrocene moiety as pendent group and have different properties compared to their only carbon‐containing counterparts. The use of PEO and polystyrene provided a matrix to spin those inorganic polymers as hybrid nanofibers which were collected in the form of a nonwoven mat. They were characterized by multinuclear NMR spectroscopy, scanning electron microscopy (SEM), and IR spectroscopy. Thermal properties of the polymers have been checked by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). 1H, 31P, and 11B NMR and IR spectroscopy revealed the nature and types of interactions of the components after co‐spinning. The SEM micrographs identify the underlying unidirectional morphology of the generated hybrid nanofibers. Nonetheless, the DSC and TGA confirmed the significant boost toward the thermal stability of the resultant multifunctional fibers. It is believed that these unique types of multifunctional electrospun nanofibers will open new avenues toward the next generation of miniaturized devices. |
| اللغة: | English |
| تدمد: | 0021-8995 1097-4628 |
| DOI: | 10.1002/app.49091⟩ |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4599d4c0d3f58eb6a2689bfde29db20e https://hal.science/hal-03160672/document |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....4599d4c0d3f58eb6a2689bfde29db20e |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 00218995 10974628 |
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| DOI: | 10.1002/app.49091⟩ |