Controlling the selective synthesis of [2]- and [3]rotaxanes by intermolecular steric hindrance between the macrocyclic hosts
| العنوان: | Controlling the selective synthesis of [2]- and [3]rotaxanes by intermolecular steric hindrance between the macrocyclic hosts |
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| المؤلفون: | Lixi Chen, Weitao Xu, Xin Xiao, Yimin Cai, Sudarshana Santhosh Kumar Kothapalli, Jian Wang, Zhiyao Yang, Zecong Ye, Wen Feng, Tinghui Zhang, Lihua Yuan, Pengchi Deng |
| المصدر: | Chemical Communications. 56:1066-1069 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | Steric effects, Stereochemistry, Chemistry, Intermolecular force, Metals and Alloys, General Chemistry, Jian wang, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Materials Chemistry, Ceramics and Composites, Side chain, Selectivity, Single crystal |
| الوصف: | Two hydrogen-bonded azo-macrocycles with little disparity of the side chains in steric hindrance exhibited a substantial difference in complexation (slow/fast exchange) towards bipyridinium. Inspired by this finding, these macrocycles were applied to efficiently and selectively construct [2]- and [3]rotaxanes through one-pot synthesis. The origin of the selectivity in this novel approach was elucidated by comparing single crystal structures, DFT calculations and stepwise synthesis. |
| تدمد: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc08253k |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::422da6ae6056262cd312a2aae31121a4 https://doi.org/10.1039/c9cc08253k |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....422da6ae6056262cd312a2aae31121a4 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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| DOI: | 10.1039/c9cc08253k |