Local impact of load cycling on degradation in polymer electrolyte fuel cells

التفاصيل البيبلوغرافية
العنوان: Local impact of load cycling on degradation in polymer electrolyte fuel cells
المؤلفون: D. Garcia-Sanchez, Renate Hiesgen, P. Gama da Rocha, Tobias Morawietz, Pawel Gazdzicki, Kaspar Andreas Friedrich
المصدر: Applied Energy
سنة النشر: 2020
مصطلحات موضوعية: Materials science, Electrical load, Scanning electron microscope, 020209 energy, Mechanical Engineering, Membrane electrode assembly, Proton exchange membrane fuel cell, 02 engineering and technology, Building and Construction, Management, Monitoring, Policy and Law, 7. Clean energy, Durability, Dynamic load testing, General Energy, Membrane, 020401 chemical engineering, Polymer electrolyte membrane fuel cell Automotive Dynamic load cycling Local degradation Pt band, 0202 electrical engineering, electronic engineering, information engineering, Degradation (geology), 0204 chemical engineering, Composite material
الوصف: Degradation mechanisms occurring during proton exchange membrane fuel cells (PEMFC) operation critically depend on the applied electrical load profile. In this work, durability tests were performed using different load cycling ranges. The tests include refresh procedures in order to recover temporary performance losses. Operando current density distribution measurements as well as electrochemical characterization techniques were applied to obtain essential data for understanding degradation behavior of the components of the membrane electrode assembly (MEA). The analysis is supported by scanning electron microscopy (SEM) and energy dispersive x-ray diffraction (EDX) analysis of MEA components. Dynamic load cycling has proven to lead to lower performance losses as compared to constant load operation. Moreover, reversible performance losses were associated with an increased heterogeneity of the current density distribution along the flow field. Thereby, areas with high local current density exhibit particularly strong Pt band formation in the membrane linked with a thinning of the cathode catalyst layer.
اللغة: English
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3fee4de29578d8acfbd4ca406136bc2f
https://elib.dlr.de/135713/
Rights: OPEN
رقم الانضمام: edsair.doi.dedup.....3fee4de29578d8acfbd4ca406136bc2f
قاعدة البيانات: OpenAIRE