Optical properties in the infrared range of the birefringent α-GeO2 single crystal
العنوان: | Optical properties in the infrared range of the birefringent α-GeO2 single crystal |
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المؤلفون: | Bertrand Ménaert, Alexandra Peña, Jean-Louis Bantignies, David Maurin, Philippe Papet, Abel Haidoux, Patrick Hermet, Pascale Armand |
المساهمون: | Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM ICMMM), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2), Laboratoire Charles Coulomb (L2C), Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Cristaux Massifs (CrisMass), Institut Néel (NEEL), Institut polytechnique de Grenoble - Grenoble Institute of Technology [2020-....] (Grenoble INP [2020-....]), Université Grenoble Alpes [2020-....] (UGA [2020-....])-Université Grenoble Alpes [2020-....] (UGA [2020-....])-Centre National de la Recherche Scientifique (CNRS)-Institut polytechnique de Grenoble - Grenoble Institute of Technology [2020-....] (Grenoble INP [2020-....]), Université Grenoble Alpes [2020-....] (UGA [2020-....])-Université Grenoble Alpes [2020-....] (UGA [2020-....])-Centre National de la Recherche Scientifique (CNRS), Optique et Matériaux (OPTIMA), Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC), Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), Université Montpellier 1 (UM1)-Université Montpellier 2 - Sciences et Techniques (UM2)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS) |
المصدر: | Materials Research Bulletin Materials Research Bulletin, Elsevier, 2020, 129, pp.110881. ⟨10.1016/j.materresbull.2020.110881⟩ |
بيانات النشر: | HAL CCSD, 2020. |
سنة النشر: | 2020 |
مصطلحات موضوعية: | optical properties, Materials science, Infrared, Infrared spectroscopy, Physics::Optics, 02 engineering and technology, [CHIM.INOR]Chemical Sciences/Inorganic chemistry, 010402 general chemistry, 01 natural sciences, Molecular physics, Spectral line, Crystal, symbols.namesake, General Materials Science, infrared spectroscopy, ComputingMilieux_MISCELLANEOUS, [PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics], Birefringence, Mechanical Engineering, [CHIM.MATE]Chemical Sciences/Material chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 0104 chemical sciences, Fourier transform, Mechanics of Materials, oxides, symbols, 0210 nano-technology, Single crystal, Refractive index |
الوصف: | International audience; The components of the frequency-dependent complex refractive index were determined indirectly for the new non-centrosymmetric α-GeO2 crystal using polarized Fourier transform infrared reflectivity spectra measured in the far- and mid-infrared spectral region at room temperature. All the longitudinal- and transverse-optical infrared active modes with E and A2 symmetry, according to the D3 point group, were identified and localized within the 100-1000 cm-1 range in very good agreement with a previous first-principles based calculation. For the A2- and E-type modes, both the longitudinal- and transverse-optical splitting were detected. The refractive indices no ( E⊥c) and ne (E //c) in the infrared domain present considerably higher values than the ones observed in the visible light range, and the high birefringence would find application in many optical devices. |
اللغة: | English |
تدمد: | 0025-5408 1873-4227 |
DOI: | 10.1016/j.materresbull.2020.110881⟩ |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::384b2193e50977d92bf2d34f55ff7d46 https://hal.archives-ouvertes.fr/hal-02949195 |
Rights: | OPEN |
رقم الانضمام: | edsair.doi.dedup.....384b2193e50977d92bf2d34f55ff7d46 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 00255408 18734227 |
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DOI: | 10.1016/j.materresbull.2020.110881⟩ |