Iridium‐Catalyzed Asymmetric Hydroarylation of Chromene Derivatives with Aromatic Ketones: Enantioselective Synthesis of 2‐Arylchromanes
| العنوان: | Iridium‐Catalyzed Asymmetric Hydroarylation of Chromene Derivatives with Aromatic Ketones: Enantioselective Synthesis of 2‐Arylchromanes |
|---|---|
| المؤلفون: | Kana Sakamoto, Takahiro Nishimura |
| المصدر: | Advanced Synthesis & Catalysis. 361:2124-2128 |
| بيانات النشر: | Wiley, 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Aromatic ketones, Enantioselective synthesis, chemistry.chemical_element, Chromanes, Asymmetric synthesis, General Chemistry, Ketones, Iridium, クロマン, Catalysis, ケトン, chemistry, イリジウム, C–H活性化, Organic chemistry, 不斉合成, C–H activation |
| الوصف: | Catalytic asymmetric hydroarylation of 2-H-chromenes with aromatic ketones was realized by use of a cationic iridium/chiral phosphine complex. The reaction proceeded via olefin isomerization, followed by enantioselective hydroarylation, thus giving 2-arylchromanes in high yields with high enantioselectivity. |
| تدمد: | 1615-4169 1615-4150 |
| DOI: | 10.1002/adsc.201801664 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2dc0c4bccdae901f0da96365ca7aee6d https://doi.org/10.1002/adsc.201801664 |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....2dc0c4bccdae901f0da96365ca7aee6d |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16154169 16154150 |
|---|---|
| DOI: | 10.1002/adsc.201801664 |