Loading across the Periodic Table: Introducing 14 Different Metal Ions To Enhance Metal–Organic Framework Performance
| العنوان: | Loading across the Periodic Table: Introducing 14 Different Metal Ions To Enhance Metal–Organic Framework Performance |
|---|---|
| المؤلفون: | Shoushun Chen, Wilson Luo, Victor V. Terskikh, Tsun-Kong Sham, Yining Huang, Bryan E. G. Lucier, Xuhui Sun, Xinkai Xie, Hendrick Chan, Kun Feng, Mark S. Workentin |
| المصدر: | ACS Applied Materials & Interfaces. 10:30296-30305 |
| بيانات النشر: | American Chemical Society (ACS), 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | Materials science, Metal ions in aqueous solution, 02 engineering and technology, 010402 general chemistry, 021001 nanoscience & nanotechnology, Co2 adsorption, 01 natural sciences, Silver nanoparticle, 0104 chemical sciences, Catalysis, Metal, visual_art, visual_art.visual_art_medium, Physical chemistry, General Materials Science, Metal-organic framework, 0210 nano-technology, Linker |
| الوصف: | Loading metal guests within metal–organic frameworks (MOFs) via secondary functional groups is a promising route for introducing or enhancing MOF performance in various applications. In this work, 14 metal ions (Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Zn2+, Co2+, Mn2+, Ag+, Cd2+, La3+, In3+, and Pb2+) have been successfully introduced within the MIL-121 MOF using a cost-efficient route involving free carboxylic groups on the linker. The local and long-range structure of the metal-loaded MOFs is characterized using multinuclear solid-state NMR and X-ray diffraction methods. Li/Mg/Ca-loaded MIL-121 and Ag nanoparticle-loaded MIL-121 exhibit enhanced H2 and CO2 adsorption; Ag nanoparticle-loaded MIL-121 also demonstrates remarkable catalytic activity in the reduction of 4-nitrophenol. |
| تدمد: | 1944-8252 1944-8244 |
| DOI: | 10.1021/acsami.8b08496 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1ce5ca07e9047b463d3be198d1af526b https://doi.org/10.1021/acsami.8b08496 |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi.dedup.....1ce5ca07e9047b463d3be198d1af526b |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 19448252 19448244 |
|---|---|
| DOI: | 10.1021/acsami.8b08496 |