Finite-Element Computer Simulations on Cyclic Voltammograms Measured at Recessed Nanodisk-Array Electrodes

التفاصيل البيبلوغرافية
العنوان: Finite-Element Computer Simulations on Cyclic Voltammograms Measured at Recessed Nanodisk-Array Electrodes
المؤلفون: Takashi Ito, Khanh Hoa Tran Ba
المصدر: ECS Meeting Abstracts. :1388-1388
بيانات النشر: The Electrochemical Society, 2012.
سنة النشر: 2012
مصطلحات موضوعية: Nanopore, Chemistry, Electrode, Analytical chemistry, Radius, Diffusion (business), Nanoscopic scale, Redox, Planar electrode, Finite element method
الوصف: The characteristics of cyclic voltammograms (CVs) at recessed nanodisk-array electrodes (RNEs) were investigated using finite-element computer simulations. Simulations were performed for RNEs based on planar electrodes coated with electrically-insulating films comprising hexagonally-distributed, vertically-oriented cylindrical nanopores (12 nm in radius, 30 nm deep). CVs and concentration profiles of redox species were simulated by varying electrode spacing (2s) and the diffusion coefficient of a redox species within the nanopores (Dpore). For nm-scale s and large Dpore, peak-shaped CVs with currents very similar to those at a film-free electrode were obtained due to the overlapping of diffusion layers extended from multiple electrodes. However, larger s and smaller Dpore gave smaller peak currents, as the nanoscale electrodes limited the number of redox species to be reacted. Further increase in s offered sigmoidal CVs though s was small enough for the overlapping of diffusion layers. These trends were consistent with experimental CVs measured at RNEs.
تدمد: 2151-2043
DOI: 10.1149/ma2012-01/38/1388
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::17f2dcf637c503ce74f98babc422d215
https://doi.org/10.1149/ma2012-01/38/1388
Rights: CLOSED
رقم الانضمام: edsair.doi.dedup.....17f2dcf637c503ce74f98babc422d215
قاعدة البيانات: OpenAIRE
الوصف
تدمد:21512043
DOI:10.1149/ma2012-01/38/1388