A binary catalyst system of a cationic Ru–CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide
| العنوان: | A binary catalyst system of a cationic Ru–CNC pincer complex with an alkali metal salt for selective hydroboration of carbon dioxide |
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| المؤلفون: | T. S. Andy Hor, He-Kuan Luo, Jie Wu, Chee Koon Ng |
| المصدر: | Chemical Communications. 52:11842-11845 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2016. |
| سنة النشر: | 2016 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Bicyclic molecule, 010405 organic chemistry, Chemistry, Inorganic chemistry, Metals and Alloys, Cationic polymerization, Salt (chemistry), General Chemistry, 010402 general chemistry, Alkali metal, 01 natural sciences, Catalysis, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Pincer movement, Hydroboration, Yield (chemistry), Polymer chemistry, Materials Chemistry, Ceramics and Composites |
| الوصف: | Binary catalyst systems comprising a cationic Ru-CNC pincer complex and an alkali metal salt were developed for selective hydroboration of CO2 utilizing pinacolborane at r.t. and 1 atm CO2, with the combination of [Ru(CNCBn)(CO)2(H)][PF6] and KOCO2tBu producing formoxyborane in 76% yield. A bicyclic catalytic mechanism was proposed and discussed. |
| تدمد: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c6cc06278d |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::099d1bd2a89a5177ce3f2a8cfe5cc419 https://doi.org/10.1039/c6cc06278d |
| رقم الانضمام: | edsair.doi.dedup.....099d1bd2a89a5177ce3f2a8cfe5cc419 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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| DOI: | 10.1039/c6cc06278d |