Highly Active Nickel Catalysts for C–H Functionalization Identified through Analysis of Off-Cycle Intermediates
| العنوان: | Highly Active Nickel Catalysts for C–H Functionalization Identified through Analysis of Off-Cycle Intermediates |
|---|---|
| المؤلفون: | Wanxiang Zhao, Alex J. Nett, Paul M. Zimmerman, John Montgomery |
| المصدر: | Journal of the American Chemical Society. 137:7636-7639 |
| بيانات النشر: | American Chemical Society (ACS), 2015. |
| سنة النشر: | 2015 |
| مصطلحات موضوعية: | Nickel, Colloid and Surface Chemistry, Chemistry, Hydride, Surface modification, Organic chemistry, chemistry.chemical_element, General Chemistry, Catalytic efficiency, Biochemistry, Catalysis |
| الوصف: | An inhibitory role of 1,5-cyclooctadiene (COD) in nickel-catalyzed C-H functionalization processes was identified and studied. The bound COD participates in C-H activation by capturing the hydride, leading to a stable off-cycle π-allyl complex that greatly diminished overall catalytic efficiency. Computational studies elucidated the origin of the effect and enabled identification of a 1,5-hexadiene-derived pre-catalyst that avoids the off-cycle intermediate and provides catalytic efficiencies that are superior to those of catalysts derived from Ni(COD)2. |
| تدمد: | 1520-5126 0002-7863 |
| DOI: | 10.1021/jacs.5b04548 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::046e396977a8d5c522b143614f8a5d46 https://doi.org/10.1021/jacs.5b04548 |
| رقم الانضمام: | edsair.doi.dedup.....046e396977a8d5c522b143614f8a5d46 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205126 00027863 |
|---|---|
| DOI: | 10.1021/jacs.5b04548 |