The pathway and kinetics of hierarchical assembly of ionic oligomers into a lyotropic columnar phase
| العنوان: | The pathway and kinetics of hierarchical assembly of ionic oligomers into a lyotropic columnar phase |
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| المؤلفون: | Shenghui Wei, Ningdong Huang, Weiheng Huang, Daan Frenkel |
| المصدر: | Soft Matter |
| مصطلحات موضوعية: | Materials science, Kinetics, Ionic bonding, 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, 0104 chemical sciences, law.invention, Supramolecular assembly, Chemical engineering, law, Phase (matter), Lyotropic, Molecule, Crystallization, 0210 nano-technology, Columnar phase |
| الوصف: | Ionic benzene-1,3,5-tricarboxamide (BTA) molecules can self-assemble into hollow cylinders which further arrange into columnar phases in water. In situ investigations suggest a multi-step pathway of supramolecular assembly via formation of dispersed molecular aggregates followed by a less ordered intermediate phase before the equilibrium columnar phase is formed. The pathway and kinetics of the formation of lyotropic LC phases through hierarchical supramolecular assembly are similar to non-classical crystallization, in line with an emerging holistic view on crystallization and self-assembly. |
| اللغة: | English |
| تدمد: | 1744-6848 1744-683X |
| DOI: | 10.1039/c9sm00383e |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::031cd35e3c0ab398a27978f76f008c25 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi.dedup.....031cd35e3c0ab398a27978f76f008c25 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 17446848 1744683X |
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| DOI: | 10.1039/c9sm00383e |