Synthesis and characterization of iridium chloride complexes: I. Use of N-alkylphenothiazine drugs as ligands
| العنوان: | Synthesis and characterization of iridium chloride complexes: I. Use of N-alkylphenothiazine drugs as ligands |
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| المؤلفون: | Netkal M. Made Gowda, Myint M. Kyi, Libo Zhang |
| المصدر: | Transition Metal Chemistry. 18:518-522 |
| بيانات النشر: | Springer Science and Business Media LLC, 1993. |
| سنة النشر: | 1993 |
| مصطلحات موضوعية: | Thermogravimetric analysis, Stereochemistry, Metals and Alloys, chemistry.chemical_element, Nuclear magnetic resonance spectroscopy, Medicinal chemistry, Magnetic susceptibility, Chloride, Catalysis, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Materials Chemistry, medicine, Molecule, Iridium, Organometallic chemistry, medicine.drug |
| الوصف: | Iridium complexes of N-alkylphenothiazines have been prepared in MeOH. The polynuclear complexes obtained have been characterized by elemental analyses, magnetic susceptibilities, molar conductivities, thermogravimetric analysis and spectral data. The molecular formulae of the new complexes are as follows: [Ir3(LH)4Cl10]Cl2·xMeOH, where L = chlorpromazine (CP), promethazine (PM) or ethopropazine (EP), and x = 1 for CP and 2 for PM or EP; [Ir(TFH2)2Cl4][IrCl6]·MeOH, where TF = trifluoperazine; and [Ir2(TRH)2Cl11(MeOH)]Cl·MeOH and [Ir4(TRH)3Cl15], where TR = thioridazine. The complexes are diamagnetic in nature. Tentative structures are proposed for the complexes. |
| تدمد: | 1572-901X 0340-4285 |
| DOI: | 10.1007/bf00136618 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::f929af31bf9b40f2399bdeee113fc6b7 https://doi.org/10.1007/bf00136618 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........f929af31bf9b40f2399bdeee113fc6b7 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1572901X 03404285 |
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| DOI: | 10.1007/bf00136618 |