This paper describes a methodology to extract effective electrical properties for periodic composite medium. The extraction algorithm is based on a periodic finite-difference time-domain (FDTD) method. The results are compared with conventional mixing theories and 3D Fourier series expansion methods. Two results show satisfactory agreement. With the extracted effective permittivity and conductivity, one can readily use these parameters to study electrical properties of composite materials with arbitrary micro-geometry and the shielding effects of using composite materials.