Lattice dynamics in kesterite-type Cu2ZnSnS4: Inelastic neutron scattering studies and thermoelectric properties

التفاصيل البيبلوغرافية
العنوان: Lattice dynamics in kesterite-type Cu2ZnSnS4: Inelastic neutron scattering studies and thermoelectric properties
المؤلفون: S. L. Chaplot, S.S. Dahiwale, Mala N. Rao, Rekha Rao, Sanjay D. Dhole, S.P. Kandare
المصدر: Journal of Physics and Chemistry of Solids. 150:109819
بيانات النشر: Elsevier BV, 2021.
سنة النشر: 2021
مصطلحات موضوعية: Materials science, Condensed matter physics, Phonon, business.industry, 02 engineering and technology, General Chemistry, engineering.material, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, Inelastic neutron scattering, 0104 chemical sciences, Condensed Matter::Materials Science, Thermal conductivity, Semiconductor, Thermal, Thermoelectric effect, engineering, General Materials Science, Crystallite, Kesterite, 0210 nano-technology, business
الوصف: Cu2ZnSnS4 is a p-type semiconductor that has been seen as a possible replacement for SnSe, Cu (In,Ga)Se2 etc. in thin film solar cells, due to non-toxicity and natural abundance of their constituent elements. Polycrystalline Cu2ZnSnS4 samples (kesterite-type) were synthesized by a microwave assisted method and investigated by inelastic neutron scattering. The experimentally measured neutron-weighted phonon density of states compares reasonably well with that estimated by a computation of the lattice dynamics. These studies are then extended to elucidate the understanding of the thermal, elastic and thermoelectric properties. The lattice-dynamics calculations are able to reproduce the temperature dependence of the thermal conductivity and the thermoelectric figure of merit, as observed in experiments previously.
تدمد: 0022-3697
DOI: 10.1016/j.jpcs.2020.109819
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::e65f29ef91c94cea168db055546ae4ef
https://doi.org/10.1016/j.jpcs.2020.109819
Rights: CLOSED
رقم الانضمام: edsair.doi...........e65f29ef91c94cea168db055546ae4ef
قاعدة البيانات: OpenAIRE
الوصف
تدمد:00223697
DOI:10.1016/j.jpcs.2020.109819