The Effect of Solvent Nature on the Adhesive Properties of Binary Styrene–n-Butyl Acrylate Copolymer Films Formed by Casting on Solid Substrates
| العنوان: | The Effect of Solvent Nature on the Adhesive Properties of Binary Styrene–n-Butyl Acrylate Copolymer Films Formed by Casting on Solid Substrates |
|---|---|
| المؤلفون: | A. A. Shcherbina, A. V. Plutalova, Elena V. Chernikova, A. V. Shapagin, Yu. V. Kostina, V. D. Dolzhikova, Yu. G. Bogdanova |
| المصدر: | Colloid Journal. 82:93-99 |
| بيانات النشر: | Pleiades Publishing Ltd, 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | Acrylate, Materials science, 010304 chemical physics, Comonomer, Radical polymerization, Chain transfer, 02 engineering and technology, Surfaces and Interfaces, 021001 nanoscience & nanotechnology, 01 natural sciences, Styrene, Solvent, chemistry.chemical_compound, Colloid and Surface Chemistry, chemistry, Chemical engineering, 0103 physical sciences, Copolymer, Adhesive, Physical and Theoretical Chemistry, 0210 nano-technology |
| الوصف: | A methodological approach has been proposed for studying the effect of solvent nature on the adhesive properties of films of binary copolymers with different chain microstructures. The approach is based on a complex analysis of the thermodynamic work of adhesion in polymer–liquid model systems and the results of mechanical tests in combination with quantum-chemical calculations. The approach has been used for the first time for copolymers of styrene and n-butyl acrylate having gradient and random distributions of comonomer units over the chains, with the copolymers being synthesized by radical polymerization with reversible chain transfer. The results obtained have shown that the adhesive properties of the binary copolymer films may be regulated by varying the chemical nature of solvents from which they are formed. |
| تدمد: | 1608-3067 1061-933X |
| DOI: | 10.1134/s1061933x20020027 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::e3d350d45035ec566798e54fcd036662 https://doi.org/10.1134/s1061933x20020027 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........e3d350d45035ec566798e54fcd036662 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16083067 1061933X |
|---|---|
| DOI: | 10.1134/s1061933x20020027 |