Pyridine, thiophosphine, and selenophosphine complexes of the phenylphosphine dication
| العنوان: | Pyridine, thiophosphine, and selenophosphine complexes of the phenylphosphine dication |
|---|---|
| المؤلفون: | Hannah Sinclair, Robert McDonald, Riccardo Suter, Neil Burford, Michael J. Ferguson |
| المصدر: | Canadian Journal of Chemistry. 96:689-693 |
| بيانات النشر: | Canadian Science Publishing, 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | 010405 organic chemistry, Organic Chemistry, General Chemistry, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, Catalysis, 0104 chemical sciences, Dication, chemistry.chemical_compound, Bipyridine, chemistry, Pyridine, Phenylphosphine |
| الوصف: | Compounds of the generic formula [PhPL][OTf]2 with L = bipyridine (bipy) and 4,4′-di(tert-butyl)-2,2′-bipyridine (Bbipy) and [PhPL2][OTf]2 with L = 4-dimethylaminopyridine (dmap), tricyclohexyl-thiophosphine, and tricyclohexyl-selenophosphine have been prepared by the reaction of dichlorophenylphosphine with two equivalents of trimethylsilyl triflate and the respective ligand. The new complexes of the phenylphosphine dication with this variety of ligands expands the scope of coordination complexes involving phosphorus as an acceptor. |
| تدمد: | 1480-3291 0008-4042 |
| DOI: | 10.1139/cjc-2017-0596 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::d208f6c0a7b7430f77139892c57d02f1 https://doi.org/10.1139/cjc-2017-0596 |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi...........d208f6c0a7b7430f77139892c57d02f1 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14803291 00084042 |
|---|---|
| DOI: | 10.1139/cjc-2017-0596 |