Poly(diketopyrrolopyrrole-benzothiadiazole) with Ambipolarity Approaching 100% Equivalency

التفاصيل البيبلوغرافية
العنوان: Poly(diketopyrrolopyrrole-benzothiadiazole) with Ambipolarity Approaching 100% Equivalency
المؤلفون: Minghong Tong, Junghoon Lee, Changduk Yang, Shinuk Cho, Jung Hwa Seo
المصدر: Advanced Functional Materials. 21:1910-1916
بيانات النشر: Wiley, 2011.
سنة النشر: 2011
مصطلحات موضوعية: chemistry.chemical_classification, Materials science, Organic field-effect transistor, business.industry, Ambipolar diffusion, Transistor, Polymer, Electron, Conjugated system, Condensed Matter Physics, Electron transport chain, Electronic, Optical and Magnetic Materials, law.invention, Biomaterials, chemistry, law, Electrochemistry, Optoelectronics, Charge carrier, business
الوصف: As a characteristic feature of conventional conjugated polymers, it has been generally agreed that conjugated polymers exhibit either high hole transport property (p-type) or high electron transport property (n-type). Although ambipolar properties have been demonstrated from specially designed conjugated polymers, only a few examples have exhibited ambipolar transport properties under limited conditions. Furthermore, there is, as yet, no example with ‘equivalent’ hole and electron transport properties. We describe the realization of an equivalent ambipolar organic field-effect transistor (FET) by using a single-component visible–near infrared absorbing diketopyrrolopyrrole (DPP)-benzothiadiazole (BTZ) copolymer, namely poly[3,6-dithiene-2-yl-2,5-di(2-decyltetradecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-5’,5’’-diyl-alt-benzo-2,1, 3-thiadiazol-4,7-diyl] (PDTDPP-alt-BTZ). PDTDPP-alt-BTZ shows not only ideally balanced charge carrier mobilities for both electrons (▴e = 0.09 cm2V−1s−1) and holes (▴h = 0.1 cm2V−1s−1) but also its inverter constructed with the combination of two identical ambipolar FETs exhibits a gain of ∼35 that is much higher than usually obtained values for unipolar logic.
تدمد: 1616-301X
DOI: 10.1002/adfm.201002651
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::d130c310dad43e4594f978e080358e2d
https://doi.org/10.1002/adfm.201002651
Rights: CLOSED
رقم الانضمام: edsair.doi...........d130c310dad43e4594f978e080358e2d
قاعدة البيانات: OpenAIRE
الوصف
تدمد:1616301X
DOI:10.1002/adfm.201002651