Influence of substrates and rutile seed layers on the assembly of hydrothermally grown rutile TiO 2 nanorod arrays

التفاصيل البيبلوغرافية
العنوان: Influence of substrates and rutile seed layers on the assembly of hydrothermally grown rutile TiO 2 nanorod arrays
المؤلفون: Berit H. Goodge, Julian Kalb, Claudia Simone Plüisch, Emily Chua, Daniela Lehr, Melanie Gerigk, Lukas Schmidt-Mende, Bastian Trepka, Alexander Wittemann, James A. Dorman, Sebastian Polarz, Christina Scheu, Alena Folger, Vanessa Knittel
المصدر: Journal of Crystal Growth. 494:26-35
بيانات النشر: Elsevier BV, 2018.
سنة النشر: 2018
مصطلحات موضوعية: Materials science, 02 engineering and technology, Substrate (electronics), Hybrid solar cell, Sputter deposition, 010402 general chemistry, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 01 natural sciences, Evaporation (deposition), 0104 chemical sciences, Inorganic Chemistry, Chemical engineering, Rutile, Materials Chemistry, Nanorod, 0210 nano-technology, Layer (electronics), Seed crystal
الوصف: Rutile TiO 2 nanorod arrays (NRAs) are applicable in various prospective technologies. Hydrothermal methods present a simple technique to fabricate such NRAs. In this report, we present the fabrication of seed layers for the hydrothermal growth of rutile TiO 2 nanorods via sputter deposition, electron-beam evaporation, and sol-gel method and study the influence of each on the growth behavior. To satisfy the requirements of numerous applications, p-type silicon, platinum, levitating carbon membranes, a template made of polystyrene spheres, and commercial fluorine tin oxide (FTO) were employed as substrates. We document the structural properties of the TiO 2 seed layers and describe the relationship between the characteristics of the seed crystals, the growth evolution, and the appearance of as-grown nanorods. Various growth stages of rutile TiO 2 nanorods are compared depending on whether they are grown on polycrystalline TiO 2 or FTO seed layers. In both cases, a homogenous TiO 2 bottom layer is formed at the seed layer/substrate interface, which is essential for electronic applications such as hybrid solar cells. Detached NRAs illustrate the effect of rutile FTO and TiO 2 on the porosity of this bottom layer. Further details about the formation process of this layer are obtained from the growth on confined seed layers fabricated by electron-beam lithography.
تدمد: 0022-0248
DOI: 10.1016/j.jcrysgro.2018.05.004
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::cf52431b335cc6bb5a5093ba19fd3718
https://doi.org/10.1016/j.jcrysgro.2018.05.004
Rights: CLOSED
رقم الانضمام: edsair.doi...........cf52431b335cc6bb5a5093ba19fd3718
قاعدة البيانات: OpenAIRE
الوصف
تدمد:00220248
DOI:10.1016/j.jcrysgro.2018.05.004