On standardization of low symmetry crystal fields

التفاصيل البيبلوغرافية
العنوان: On standardization of low symmetry crystal fields
المؤلفون: Z. Gajek
المصدر: Journal of Physics and Chemistry of Solids. 82:21-27
بيانات النشر: Elsevier BV, 2015.
سنة النشر: 2015
مصطلحات موضوعية: Standardization, Condensed matter physics, Chemistry, Spin hamiltonian, General Chemistry, Triclinic crystal system, Condensed Matter Physics, Crystal, Crystallography, Optical materials, General Materials Science, Orthorhombic crystal system, Low symmetry, Monoclinic crystal system
الوصف: Standardization methods of low symmetry – orthorhombic, monoclinic and triclinic – crystal fields are formulated and discussed. Two alternative approaches are presented, the conventional one, based on the second-rank parameters and the standardization based on the fourth-rank parameters. Mainly f-electron systems are considered but some guidelines for d-electron systems and the spin Hamiltonian describing the zero-field splitting are given. The discussion focuses on premises for choosing the most suitable method, in particular on inadequacy of the conventional one. Few examples from the literature illustrate this situation.
تدمد: 0022-3697
DOI: 10.1016/j.jpcs.2015.02.010
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::ce426752f3c767e94d4fcb98afad957b
https://doi.org/10.1016/j.jpcs.2015.02.010
Rights: CLOSED
رقم الانضمام: edsair.doi...........ce426752f3c767e94d4fcb98afad957b
قاعدة البيانات: OpenAIRE
الوصف
تدمد:00223697
DOI:10.1016/j.jpcs.2015.02.010