Synthesis and crystal structure of [1,3- N , N -bis{2,6-diisopropylphenyl}imidazol-2-ylidene]chloro-[ N , N -dimethylbenzylamine-2- C , N ]palladium(II)
| العنوان: | Synthesis and crystal structure of [1,3- N , N -bis{2,6-diisopropylphenyl}imidazol-2-ylidene]chloro-[ N , N -dimethylbenzylamine-2- C , N ]palladium(II) |
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| المؤلفون: | Xin-Hua Cao, Hong-Wei Yu, Ji-Cheng Shi, Ying Zheng |
| المصدر: | Journal of Coordination Chemistry. 60:207-211 |
| بيانات النشر: | Informa UK Limited, 2007. |
| سنة النشر: | 2007 |
| مصطلحات موضوعية: | Ligand, Trans effect, chemistry.chemical_element, Crystal structure, Dimethylbenzylamine, chemistry.chemical_compound, Crystallography, chemistry, Materials Chemistry, Physical and Theoretical Chemistry, Carbon, Isopropyl, Palladium, Monoclinic crystal system |
| الوصف: | The title compound 1 has been synthesized and its structure has been determined by single-crystal X-ray methods. Crystal data: C36H48ClN3Pd, M = 664.62, monoclinic, space group P21/n with a = 11.857(5), b = 21.042(8), c = 14.632(6) A, β = 106.492(5), Z = 4, V = 3501(2) A3, D c = 1.261 g cm−3, μ(Mo-Kα) = 0.633 mm−1, F(000) = 1392; final R and wR = 0.0412 and 0.0889, respectively, for 3265 observed reflections with I ≥ 2σ(I). The Pd(II) atom has distorted square planar geometry, due to the bulk of the isopropyl groups on the NHC ligand. Positioning of the carbenic carbon trans to the amino group and the metalated carbon trans to chlorine is consist with the trans influence. |
| تدمد: | 1029-0389 0095-8972 |
| DOI: | 10.1080/00958970600763557 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::bc6183b9466fd7affdf878b1b182df66 https://doi.org/10.1080/00958970600763557 |
| رقم الانضمام: | edsair.doi...........bc6183b9466fd7affdf878b1b182df66 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10290389 00958972 |
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| DOI: | 10.1080/00958970600763557 |