Binuclear Mixed Valence Oxovanadium( IV / V ) Complexes Containing a [OV IV (μ‐O oxo )(μ‐O phen )V V O] 2+ Core: Synthesis, EPR Spectra, Molecular and Electronic Structure
| العنوان: | Binuclear Mixed Valence Oxovanadium( |
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| المؤلفون: | Amrita Mondal, Ranjan Das, Deepak Chopra, Kajal Krishna Rajak, Sucharita Basak, Sumana Sarkar |
| المصدر: | European Journal of Inorganic Chemistry. 2006:1824-1829 |
| بيانات النشر: | Wiley, 2006. |
| سنة النشر: | 2006 |
| مصطلحات موضوعية: | Valence (chemistry), Vanadium, chemistry.chemical_element, Oxovanadium IV, Electronic structure, Spectral line, law.invention, Inorganic Chemistry, Crystallography, Unpaired electron, chemistry, Computational chemistry, law, Molecule, Electron paramagnetic resonance |
| الوصف: | Binuclear mixed valence oxovanadium(IV/v) complexes of general formula [V2O3L] containing a [OVIV(μ-Ooxo)(μ-Ophen)VVO]2+ core have been synthesised using conformationally labile N4O3-coordinating heptadentate ligands (H3L). The X-ray structure of one complex has been examined. Solution EPR spectra revealed that the unpaired electron of the complexes is delocalised between the two vanadium centres. The simulated EPR spectrum of one complex confirms this experimental observation. DFT studies have been performed using crystallographic coordinates in order to obtain further insight into the electronic structure of this type of molecule. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) |
| تدمد: | 1099-0682 1434-1948 |
| DOI: | 10.1002/ejic.200500753 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::b77245d8234ac15bf1a5eff777566fcd https://doi.org/10.1002/ejic.200500753 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........b77245d8234ac15bf1a5eff777566fcd |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10990682 14341948 |
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| DOI: | 10.1002/ejic.200500753 |