Superbase/Acylamido-Based Deep Eutectic Solvents for Multiple-Site Efficient CO2 Absorption
| العنوان: | Superbase/Acylamido-Based Deep Eutectic Solvents for Multiple-Site Efficient CO2 Absorption |
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| المؤلفون: | Na Yang, Luhong Zhang, Yongli Sun, Na Zhang, Xiaowei Tantai, Jingwen Ma, Zhaohe Huang, Bin Jiang |
| المصدر: | Energy & Fuels. 33:7569-7577 |
| بيانات النشر: | American Chemical Society (ACS), 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | Materials science, Infrared, General Chemical Engineering, Superbase, Energy Engineering and Power Technology, 02 engineering and technology, Carbon-13 NMR, 021001 nanoscience & nanotechnology, Fuel Technology, 020401 chemical engineering, Desorption, Atom, Proton NMR, Physical chemistry, 0204 chemical engineering, Absorption (chemistry), 0210 nano-technology, Eutectic system |
| الوصف: | Deep eutectic solvents (DESs) have been regarded as promising alternative absorbents for CO2 capture recently. In this work, a series of novel superbase/acylamido-based DESs with low viscosity were synthesized and used for CO2 capture. 1,5-Diazabicyclo[4.3.0]non-5-ene (DBN)/2-imidazolidone (EU) (2:1) exhibited fairly high absorption capacity up to 23.02 wt % (1.75 mol CO2 per mol DES) at 45 °C and 1 bar. Furthermore, the absorbent showed high desorption efficiency and excellent recycling performance during five absorption–desorption cycles. Fourier transform infrared, 1H NMR, and 13C NMR spectra analyses and quantum chemical calculations were used to investigate the interaction mechanism between the DES and CO2. The enhanced CO2 absorption capacity can be ascribed to the strong multiple-site interaction between the N atom of EU and CO2. This work supplies a new strategy to design and optimize high-efficiency superbase/acylamido-based DESs for CO2 capture. |
| تدمد: | 1520-5029 0887-0624 |
| DOI: | 10.1021/acs.energyfuels.9b01361 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::b5e5826103174b0d16182f70d56ab0ae https://doi.org/10.1021/acs.energyfuels.9b01361 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........b5e5826103174b0d16182f70d56ab0ae |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205029 08870624 |
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| DOI: | 10.1021/acs.energyfuels.9b01361 |