Kinetics of thermal conversions of monoterpenic compounds in supercritical lower alcohols
| العنوان: | Kinetics of thermal conversions of monoterpenic compounds in supercritical lower alcohols |
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| المؤلفون: | A. Ermakova, V. I. Anikeev, Andrey M. Chibiryaev, Ivan V. Kozhevnikov |
| المصدر: | Kinetics and Catalysis. 51:162-193 |
| بيانات النشر: | Pleiades Publishing Ltd, 2010. |
| سنة النشر: | 2010 |
| مصطلحات موضوعية: | Chemistry, Kinetics, Turpentine, General Chemistry, Catalysis, Supercritical fluid, Computer Science Applications, Terpene, Solvent, Modeling and Simulation, Phase (matter), Organic chemistry, Selectivity |
| الوصف: | The most important information concerning thermal conversions of vegetable terpenes (α-pinene, β-pinene, turpentine, and cis-verbenol) in supercritical lower alcohols is systematized. The kinetics of selected reactions is reported and is compared with the kinetics of the same reactions in the gas and liquid phases. Thermodynamic calculations of the phase states and kinetic parameters are presented for a number of multicomponent multiphase systems containing terpenes and lower alcohols. The effect of the supercritical solvent pressure on the rate and selectivity of the selected reactions is reported. |
| تدمد: | 1608-3210 0023-1584 |
| DOI: | 10.1134/s0023158410020035 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::b319ab4c7463cb53025be8c7937f67e2 https://doi.org/10.1134/s0023158410020035 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........b319ab4c7463cb53025be8c7937f67e2 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16083210 00231584 |
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| DOI: | 10.1134/s0023158410020035 |