Oxidation of pyrrole with p-benzoquinone to semiconducting products and their application in electrorheology
| العنوان: | Oxidation of pyrrole with p-benzoquinone to semiconducting products and their application in electrorheology |
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| المؤلفون: | Miroslav Mrlik, Zuzana Walterová, Jiří Horský, Jaroslav Stejskal, Sergey K. Filippov, Tomáš Plachý, Patrycja Bober, Miroslava Trchová |
| المصدر: | New Journal of Chemistry. 42:10167-10176 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | Aqueous solution, Inorganic chemistry, 02 engineering and technology, General Chemistry, Conductivity, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, Benzoquinone, Methanesulfonic acid, Catalysis, 0104 chemical sciences, Dielectric spectroscopy, chemistry.chemical_compound, symbols.namesake, chemistry, Quinhydrone electrode, Materials Chemistry, symbols, 0210 nano-technology, Raman spectroscopy, Pyrrole |
| الوصف: | A low-molecular-weight organic semiconducting material was prepared by the redox interaction between pyrrole and p-benzoquinone. The reaction between pyrrole and p-benzoquinone in aqueous solutions of methanesulfonic acid proceeded smoothly at room temperature. The product with a globular morphology obtained in high yield in 0.1 M methanesulfonic acid had the highest conductivity, 4.6 × 10−6 S cm−1. On the other hand, the samples prepared in the absence of acid or at high acid concentration were non-conducting. EPR spectroscopy confirmed the presence of electronic species as charge carriers responsible for conductivity. The dominating component was proved to be a low-molecular-weight adduct composed of the quinhydrone complex and the pyrrole molecule. FTIR and Raman spectra were used to discuss the molecular structure in detail. A strong electrorheological effect with a very fast response time was demonstrated by the reproducible increase in the viscosity of suspensions in silicone oil after application of the electric field. The effect is discussed with the help of dielectric spectroscopy. |
| تدمد: | 1369-9261 1144-0546 |
| DOI: | 10.1039/c8nj01283k |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::a469a45586b874f853078e6c4377f01d https://doi.org/10.1039/c8nj01283k |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi...........a469a45586b874f853078e6c4377f01d |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 13699261 11440546 |
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| DOI: | 10.1039/c8nj01283k |