Syntheses, Crystal Structures, and Antimicrobial Activities of Copper(II) Complexes Derived from N,N'-Bis(5-Fluorosalicylidene)-1,3-Propanediamine
| العنوان: | Syntheses, Crystal Structures, and Antimicrobial Activities of Copper(II) Complexes Derived from N,N'-Bis(5-Fluorosalicylidene)-1,3-Propanediamine |
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| المؤلفون: | Guo-Wei Zang, Li-Jie Li, F. M. Wang, Tong-Tong Deng, Z. L. You |
| المصدر: | Russian Journal of Coordination Chemistry. 47:225-233 |
| بيانات النشر: | Pleiades Publishing Ltd, 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Schiff base, Ligand, General Chemical Engineering, chemistry.chemical_element, General Chemistry, Crystal structure, Antimicrobial, Medicinal chemistry, Copper, Electron spectroscopy, Square pyramidal molecular geometry, chemistry.chemical_compound, chemistry, Single crystal |
| الوصف: | Two new Schiff base copper(II) complexes, [Cu2L2] (I) and [Cu2L(NCNCN)2]n (II), where L is the dianionic form of N,N'-bis(5-fluorosalicylidene)-1,3-propanediamine (H2L), were synthesized and characterized by elemental analyses, infrared and electronic spectroscopy, and single crystal X-ray determinations (CIF files CCDC. nos. 2000415 (I) and 2000416 (II)). Complex I is a phenolate bridged dinuclear copper(II) compound. Complex II is a phenolate and dicyanoamide bridged polynuclear copper(II) compound. In both complexes, the Cu atoms are in square pyramidal coordination. The Schiff base ligand coordinates to the Cu atoms through the phenolate O and imino N atoms. The Schiff base H2L and the two complexes showed high selectivity and antimicrobial activities against a number of the bacteria and fungi. |
| تدمد: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328421030076 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::a22caa4ae642592ff0591dbcf01c2394 https://doi.org/10.1134/s1070328421030076 |
| Rights: | CLOSED |
| رقم الانضمام: | edsair.doi...........a22caa4ae642592ff0591dbcf01c2394 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 16083318 10703284 |
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| DOI: | 10.1134/s1070328421030076 |