Mechanochemical synthesis of freebase and metal corroles
| العنوان: | Mechanochemical synthesis of freebase and metal corroles |
|---|---|
| المؤلفون: | Wolfgang Schöfberger, Michael Haas, Ian Teasdale, Oliver Brüggemann, Adrian Dorniak |
| المصدر: | Journal of Porphyrins and Phthalocyanines. 26:84-89 |
| بيانات النشر: | World Scientific Pub Co Pte Ltd, 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Benzaldehyde, Metal, chemistry.chemical_compound, Chemistry, visual_art, Mechanochemistry, visual_art.visual_art_medium, General Chemistry, Combinatorial chemistry, Pyrrole |
| الوصف: | Herein, we report on the mechanochemical reaction of pyrrole and substituted benzaldehyde precursors to produce freebase corroles and demonstrate the one-pot mechanochemical synthesis of 5,10,15-Tris(4-[Formula: see text]-butylphenyl)corrole (H[Formula: see text]-buPhC), in which both, the condensation and oxidation reactions steps, took place in the ball mill. Moreover, we could achieve the mechanochemical synthesis of copper corroles with decent overall yields of 10–12%. With the mechanochemical approach we could shift the EcoScale obtained from common synthesis procedures to significant more positive values and the E-factor for the mechanochemical copper insertion was lowered by factor of 3.0. |
| تدمد: | 1099-1409 1088-4246 |
| DOI: | 10.1142/s1088424621501145 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::89fbe30fdf7d118db7077f9740e33fe8 https://doi.org/10.1142/s1088424621501145 |
| Rights: | OPEN |
| رقم الانضمام: | edsair.doi...........89fbe30fdf7d118db7077f9740e33fe8 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 10991409 10884246 |
|---|---|
| DOI: | 10.1142/s1088424621501145 |