Sub-Optical-Cycle Light-Matter Energy Transfer Dynamics in Molecular Vibrational Spectroscopy

التفاصيل البيبلوغرافية
العنوان: Sub-Optical-Cycle Light-Matter Energy Transfer Dynamics in Molecular Vibrational Spectroscopy
المؤلفون: Maximilian Högner, Regina de Vivie-Riedle, Theresa Buberl, Martin Peschel, Ioachim Pupeza
المصدر: 2021 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC).
بيانات النشر: IEEE, 2021.
سنة النشر: 2021
مصطلحات موضوعية: Materials science, Picosecond, Attenuation, Physics::Optics, Infrared spectroscopy, Light beam, Stimulated emission, Physics::Chemical Physics, Absorption (electromagnetic radiation), Spectroscopy, Molecular physics, Excitation
الوصف: Frequency-domain molecular absorption spectroscopies compare the energy spectral density of a light beam before and after interaction with resonant molecules in a limited spectral range, yielding the wavelength-resolved sample-specific attenuation. However, in these schemes, temporal integration hides the dynamics of the interaction between the electric field of the excitation and the sample. Here, we employ attosecond-precision electric-field-resolved spectroscopy to trace the complete energy transfer dynamics between mid-infrared (MIR) optical waveforms and vibrating methylsulfonylmethane (DMSO2) molecules in aqueous solution, with sub-cycle resolution. Resonant absorption and stimulated emission are observed on a few-femtosecond scale and optical-phase-dependent coherent transients manifest on the femtosecond-to-picosecond scale. The oscillations of the coherently-excited molecules dephase within several picoseconds owing to their varying environments in the solution.
DOI: 10.1109/cleo/europe-eqec52157.2021.9542424
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::846a84355a3ad642097b5ae1165927ba
https://doi.org/10.1109/cleo/europe-eqec52157.2021.9542424
Rights: CLOSED
رقم الانضمام: edsair.doi...........846a84355a3ad642097b5ae1165927ba
قاعدة البيانات: OpenAIRE
الوصف
DOI:10.1109/cleo/europe-eqec52157.2021.9542424