Observation of fine structure and hyperfine structure depolarization in the photofragment anisotropy in triplet H2

التفاصيل البيبلوغرافية
العنوان: Observation of fine structure and hyperfine structure depolarization in the photofragment anisotropy in triplet H2
المؤلفون: Wim J. van der Zande, Katharine L. Reid, B. Buijsse, Laurens D.A. Siebbeles, Eloy R. Wouters
المصدر: Chemical Physics. 218:309-323
بيانات النشر: Elsevier BV, 1997.
سنة النشر: 1997
مصطلحات موضوعية: Chemistry, Total angular momentum quantum number, Excited state, Precession, General Physics and Astronomy, Depolarization, Physics::Chemical Physics, Physical and Theoretical Chemistry, Atomic physics, Spin (physics), Spectroscopy, Anisotropy, Hyperfine structure
الوصف: Electron spin and nuclear spin reduce the anisotropy of photofragments in relatively long-lived levels of the g3Σg+ and i3∏g states of the n = 3 triplet gerade system of molecular hydrogen. The intramolecular forces due to the spin result in a precession of the plane of rotation around the total angular momentum vector. The photofragment anisotropy reveals whether the excited state lifetime allows for this precession to occur, hence whether the fine and hyperfine structure are resolvable. In partially fine structure resolved experiments, using fast beam photofragment spectroscopy, this fine and hyperfine structure depolarization is observed. The theory behind the depolarization is presented as well.
تدمد: 0301-0104
DOI: 10.1016/s0301-0104(97)00082-7
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::7a671caca93594a384485a589b3b5dea
https://doi.org/10.1016/s0301-0104(97)00082-7
Rights: CLOSED
رقم الانضمام: edsair.doi...........7a671caca93594a384485a589b3b5dea
قاعدة البيانات: OpenAIRE
الوصف
تدمد:03010104
DOI:10.1016/s0301-0104(97)00082-7