Cyclopentenone formation via hydrogen activation in the reactions of chromium carbene complexes with alkynes
| العنوان: | Cyclopentenone formation via hydrogen activation in the reactions of chromium carbene complexes with alkynes |
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| المؤلفون: | Cynthia A. Challener, Steven Chamberlin, Stephen D. Darling, Christopher K. Murray, Benjamin Alan Anderson, Katherine L. Faron, Dominic C. Yang, Oak K. Kim, William D. Wulff, Yao Chang Xu |
| المصدر: | Journal of the American Chemical Society. 115:1359-1376 |
| بيانات النشر: | American Chemical Society (ACS), 1993. |
| سنة النشر: | 1993 |
| مصطلحات موضوعية: | chemistry.chemical_classification, Olefin fiber, Chemistry, Hydride, chemistry.chemical_element, General Chemistry, Tungsten, Biochemistry, Catalysis, Reductive elimination, Chromium, chemistry.chemical_compound, Colloid and Surface Chemistry, Molybdenum, Polymer chemistry, Carbene, Alkyl |
| الوصف: | The reactions of alkyl chromium carbene complexes with alkynes have been found to give cyclopentenones. Mechanisms are proposed to account for the formation of these products that involve metal hydride intermediates. As has been previously reported for tungsten, molybdenum alkyl complexes have been found to give 1,3-dienes rather than cyclopentenones. The difference between chromium and molybdenum and tungsten may be that a metal hydride intermediate can re-add to an olefin in the case of chromium rather than undergo reductive elimination |
| تدمد: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00057a020 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::78ba5bcc271e46ac6b622fee89d080f1 https://doi.org/10.1021/ja00057a020 |
| رقم الانضمام: | edsair.doi...........78ba5bcc271e46ac6b622fee89d080f1 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15205126 00027863 |
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| DOI: | 10.1021/ja00057a020 |