Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex
| العنوان: | Actinide Metallocene Hydride Chemistry: C–H Activation in Tetramethylcyclopentadienyl Ligands to Form [μ-η5-C5Me3H(CH2)-κC]2– Tuck-over Ligands in a Tetrathorium Octahydride Complex |
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| المؤلفون: | Joseph W. Ziller, Daniel J. Grant, Justin R. Walensky, Nathan A. Siladke, Michael K. Takase, William J. Evans, Laura Gagliardi, Christopher L. Webster |
| المصدر: | Organometallics. 32:6522-6531 |
| بيانات النشر: | American Chemical Society (ACS), 2013. |
| سنة النشر: | 2013 |
| مصطلحات موضوعية: | Chemistry, Hydride, Organic Chemistry, Actinide, Medicinal chemistry, Inorganic Chemistry, Metal, chemistry.chemical_compound, Hydrogenolysis, visual_art, visual_art.visual_art_medium, Organic chemistry, Reactivity (chemistry), Physical and Theoretical Chemistry, Metallocene |
| الوصف: | Hydrogenolysis of the dimethyl actinide metal- locenes (C5Me4SiMe3)2UMe2 and (C5Me4H)2AnMe2 (An = Th, U) was examined for comparison with the hydrogenolysis of (C5Me5)2AnMe2 that forms the hydrides ((C5Me5)2ThH2)2, ((C5Me5)2UH2)2, and ((C5Me5)2UH)2. Parallel reactivity is not found with the (C5Me4SiMe3) � and (C5Me4H) � |
| تدمد: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om4008482 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::718c2256f69467f5bd684a6608950cd9 https://doi.org/10.1021/om4008482 |
| رقم الانضمام: | edsair.doi...........718c2256f69467f5bd684a6608950cd9 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15206041 02767333 |
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| DOI: | 10.1021/om4008482 |